An improved evolutionary algorithm for complex-process optimization(IEACOP) is presented to achieve optimal setting of load distribution about hot rolling mill. The algorithm is partially based on the principles of the scatter search, which has flexible structure and is embedded in sub-methods that have search mechanism. Meanwhile, infinite folding chaotic model and local search method are applied to improve initial population strategy and “go-beyond strategy” of indepth search. Then the efficiency of the local optimal solution is improved. The experiment results show that IEACOP makes use of fewer adjustable parameters to get feasible mathematical solution for the actual load distribution problems and validate the real-time application, which is the organism including local search and global search.