This paper presents a transportation and distribution model of emergency materials for a three-layer relief transportation network after analyzing the practice of emergency management. The model aims at minimizing the system losses and meets the constraints of emergency response time and fairness constraint. A modified particle swarm optimization algorithm is proposed for the integer nonlinear programming,the spatial search abilities of the particles are improved by determining different learning objects for different dimensions of the particles. Finally, a numerical example verifies the effectiveness of the model and the algorithm.