A hybrid multi-attribute risk decision analysis method considering decision maker’s behavioral factors is proposed to solve the emergency plan selection problem. Firstly, basic paradigms of decision information structures of the problem are induced. Then, the value function of prospect theory is applied to calculate the prospect value of each alternative property under the thought of pair-wise comparison of choice schemes and cross judgment of basic situations. Furthermore, the overall value of each plan is calculated to determine a ranking of alternatives based on the two-tuple model. Finally, examples are given to demonstrate the effectiveness and feasibility of the proposed method.